METHOD FOR MAKING ISOPRENE POLYMERISATION CATALYST Russian patent published in 2009 - IPC B01J37/04 C08F4/44 C08F136/08 

Abstract RU 2354450 C1

FIELD: chemistry.

SUBSTANCE: invention refers to making synthetic rubber and can be used in petrochemical industry. There is disclosed method for making isoprene polymerisation catalyst by interaction of compound neodymium and alkylaluminium, alkylaluminium halogenide and coupled diene in hydrocarbon solvent as added to compound neodymium in any sequence in mole ratio neodymium: aluminium: chlorine: diene 1: 2-20: 2-3: 8-25 thereafter kept within 2-24 hours. The method is characterised that before mixed with catalyst components, compound neodymium is pre-reacted with multinuclear alcohol taken in amount 10-100 mol. % in ratio to neodymium.

EFFECT: introduction of multinuclear alcohol that allows 12-36% improving catalytic activity systems in polyisoprene synthesis.

2 cl, 10 ex

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RU 2 354 450 C1

Authors

Orlov Jurij Nikolaevich

Dul'Kina Svetlana Alekseevna

Shitova Irina Vladislavovna

Andrijanov Vladimir Anatol'Evich

Zhdanov Ildus Linizovich

Peshekhonov Igor' Jur'Evich

Fedotov Jurij Ivanovich

Dates

2009-05-10Published

2008-01-09Filed