FIELD: chemistry.
SUBSTANCE: invention concerns method of obtaining novel organic aluminium compounds, 9-chloro-10,11-dialkyl-9-aluminabicyclo[6,3,0]undeca-1(8),10-dienes. Method involves reaction of equimolar cyclooctene and dialkylacetylene mix with aluminium trichloride in the presence of magnesium (powder) and zirconocene dichloride catalyst in argon atmosphere at room temperature in tetrahydrofuran for 8-12 hours.
EFFECT: claimed compound can be applied as catalytic system component in oligomerisation and polymerisation processes for olefin, diene and acetylene hydrocarbons, and in fineorganic and metal-organic synthesis.
1 cl, 1 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 10,11-DIALKYL-9-MAGNESABICYCLO[6,3,0]UNDECA-1(8),10-DIENES | 2007 |
|
RU2355695C2 |
| METHOD OF OBTAINING 10-ETHYL-11,12-DIALKYL-10-ALUMINABICYCLO [7,3,0]DODECA-8,11-DIENES | 2007 |
|
RU2348640C1 |
| METHOD OF PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABICYCLO[6,3,0]UNDEC-1(8)-ENES | 2008 |
|
RU2373214C1 |
| METHOD OF PRODUCING 10-ALKYL-12-ETHYL-12-ALUMINABICYCLO[7.3.0]DODEC-1( 2 )-ENES | 2008 |
|
RU2375368C2 |
| METHOD OF OBTAINING 7-CHLORO-1,2,3,4,5,6,7,8,9,10,11,12,13-DODECAHYDRODICYCLO-OCTA-[b,d]-ALUMINACYCLOPENTADIENE | 2007 |
|
RU2342394C2 |
| METHOD OF PRODUCING 11-ETHYL-11-ALUMINATETRACYCLO[11.2.1.0.0]HEXADEC-3( 10 )-ENE | 2008 |
|
RU2375366C2 |
| METHOD OF PRODUCING 11,12-DIALKYL-10-MAGNESABICYCLO[7.3.0]DODECA-8,11-DIENES | 2007 |
|
RU2349594C1 |
| METHOD FOR PREPARING 10-CHLORO-1,7,8,9-TETRAALKYL-4-METHYL-4-AZA-10-ALUMINATRICYCLO[5.2.1.0]DEC-8-ENE-3,5-DIONES | 2005 |
|
RU2295529C1 |
| METHOD OF PRODUCING 11-CHLORO-11-ALUMINA-TRICYCLO [10.7.0.0]NONADECA-9,12-DIENE | 2007 |
|
RU2349595C1 |
| METHOD FOR PREPARING 11-CHLORO-1,8,9,10-TETRAALKYL-11-ALUMINATRICYCLO[6.2.1.0]UNDEC-9-ENE-3,6-DIONES | 2005 |
|
RU2295530C1 |
