FIELD: chemistry.
SUBSTANCE: method is described for producing 11-ethyl-11aluminatetracyclo [11.2.1.02.12.04.11]-hexadec-3(10)-ene (1). The method involves reacting an equimolar mixture of cycooctyne and norbornene with ethylaluminium dichloride in the presence of magnesium (powder) and a zirconocene dichloride catalyst in an argon atmosphere at room temperature for 8 to 12 hours.
EFFECT: proposed method allows for obtaining a new compound with high regioselectivity and high output 62-74%.
1 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABICYCLO[6,3,0]UNDEC-1(8)-ENES | 2008 |
|
RU2373214C1 |
| METHOD OF PRODUCING 3-ETHYL-3-ALUMINATETRACYCLO[12.2.1.0.0]HEPTADEC-4-ENE | 2008 |
|
RU2375367C2 |
| METHOD FOR PREPARING 11-CHLORO-1,8,9,10-TETRAALKYL-11-ALUMINATRICYCLO[6.2.1.0]UNDEC-9-ENE-3,6-DIONES | 2005 |
|
RU2295530C1 |
| METHOD OF PRODUCING 10-ALKYL-12-ETHYL-12-ALUMINABICYCLO[7.3.0]DODEC-1( 2 )-ENES | 2008 |
|
RU2375368C2 |
| METHOD OF OBTAINING 1-ETHYL-2,3,4,5,6,7,8,9-OCTAHYDRO-1H-CYCLOOCTA-[b]-ALUMINACYCLOPENTANE | 2007 |
|
RU2342395C2 |
| METHOD OF COMBINED PRODUCTION OF 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,16-DIENE AND 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,17-DIENE | 2008 |
|
RU2375369C2 |
| METHOD FOR PREPARING 10-CHLORO-1,7,8,9-TETRAALKYL-4-METHYL-4-AZA-10-ALUMINATRICYCLO[5.2.1.0]DEC-8-ENE-3,5-DIONES | 2005 |
|
RU2295529C1 |
| METHOD FOR PREPARING 1,7,8,9-TETRAALKYL-10-ETHYL-4-OXO-10-ALUMINATRICYCLO[5,2,1,0]-DEC-8-ENE-3,5-DIONES | 2004 |
|
RU2275374C2 |
| METHOD FOR PREPARING 15-CHLORO-1,12,13,14-TETRAALKYL-15-ALUMINATETRACYCLO[10.2.1.0.0]PENTADECA-4(9),5,7,13-TETRAENE-3,10-DIONES | 2005 |
|
RU2295531C1 |
| METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE | 2004 |
|
RU2280037C2 |
