FIELD: chemistry.
SUBSTANCE: invention relates to hydroxyphenyltriazine UV-radiation absorbents for protecting transparent plastic containers or films and their contents. Description is given of oligoester or polyester with general formula -[A-O-D-O]x- as an additive to thermoplastic polymer material, where x - ranges from 1 to 50; A - is a hydroxytriphenyltriazine residue with formula (II) or assumes one of the values, indicated for T; D - C4-C12alkylene, which can be substituted with OH, and/or include O; L - C1-C18alkylene; C5-C12cycloalkylene; C3-C18 alkenylene, which can be substituted with phenyl, C7-C11alkylphenyl, C5-C12cycloalkyl, OH, halogen, C1-C18alkoxy group, C5-C12cyclolkoxy group, C3-C18alkenyloxy group, COOH; R1 - H, OR7 or OH under the condition that, at least one of R1 or R13 represents OH; R7 - hydrogen, C1-C12alkyl or L-CO-O-R9, where R9 - H, C1-C18alkyl, C2-C12hydroxyalkyl; R10 - hydrogen, C1-C4alkyl, Cl, phenyl or -OR7; R11 - hydrogen, methyl; R13 - hydrogen, methyl, OH, OR7; and T - is a bivalent acyl residue of aliphatic or cycloaliphatic C13-C60 dicarboxylic acid, and which includes at least one fragment with formula (II) and at least one fragment T.
EFFECT: effective protection of products in thin-walled containers or films.
13 cl, 8 ex
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Authors
Dates
2009-10-20—Published
2004-05-14—Filed