FIELD: chemistry.
SUBSTANCE: invention relates to vanadium-titanium oxide catalysts, used for producing nicotinic acid through gas phase oxidation of β-picoline with oxygen and methods of producing nicotinic acid using said catalysts. The catalyst contains vanadium oxide, titanium oxide and modifying additives - cerium oxide or one or more metal oxides, chosen from groups IV and V of the periodic table of elements with total content of oxides of modifying elements in the range 1.0 to10.0 wt %, vanadium oxide in amount of 5.0 to 75.0 wt %, and titanium oxide - the rest. A method is described for producing nicotinic acid through oxidation of β-picoline with oxygen in one or more successive layers of catalyst with different grain-size in a tube reactor in the presence of the catalyst described above.
EFFECT: increased activity of catalyst and selectivity on nicotinic acid.
13 cl, 2 tbl, 15 ex
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Authors
Dates
2009-10-27—Published
2008-06-10—Filed