FIELD: chemistry.
SUBSTANCE: invention relates to a method of purifying chloroform through its treatment with a mixture of gaseous sulphuric anhydride with air, obtained by passing air through oleum heated to temperature 30°C-60°C. Treatment is carried out at temperature 20°C-50°C for 2-7 hours and content of sulphuric anhydride in the gaseous mixture of 20-50 wt %.
EFFECT: obtaining high-quality chloroform, in which not only 1,1-dichloroethane is absent, but cis- and trans-dichloroethane as well, considerable reduction of waste water and gaseous emissions, reduction of raw material consumption.
1 cl, 1 ex, 3 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PURIFICATION OF CHLOROFORM | 1994 |
|
RU2081868C1 |
METHOD FOR PURIFICATION OF CHLOROFORM | 1995 |
|
RU2096400C1 |
METHOD OF CHLOROFORM PURIFICATION | 2007 |
|
RU2332395C1 |
METHOD OF SYNTHESIS OF CHLOROFORM | 1999 |
|
RU2165917C1 |
METHOD OF PRODUCING CHLOROMETHANES | 2007 |
|
RU2358961C1 |
0 |
|
SU247279A1 | |
HYDROGEN FLUORIDE PRODUCTION PROCESS AND INSTALLATION | 2005 |
|
RU2287480C1 |
PROCESS FOR PREPARING METHANIC CHLOROHYDROCARBONS | 1996 |
|
RU2127245C1 |
METHOD OF RECYCLING CHLORORGANIC WASTES | 2013 |
|
RU2560773C2 |
METHOD OF OBTAINING 1,2-DICHLORETHANE | 1977 |
|
SU728372A1 |
Authors
Dates
2011-04-27—Published
2009-03-31—Filed