TRANSITION METAL-BASED NANOCATALYST, PREPARATION METHOD THEREOF AND USE IN FISCHER-TROPSCH SYNTHESIS REACTIONS Russian patent published in 2011 - IPC B01J23/46 B01J23/74 B01J31/06 B01J35/12 B01J37/04 B82B3/00 C07C1/04 

Abstract RU 2430780 C2

FIELD: chemistry.

SUBSTANCE: invention relates to Fishcher-Tropsch synthesis catalysts. Described is a transition metal-based nanocatalyst for Fischer-Tropsch synthesis, which contains nanoparticles of a transition metal and polymer stabilisers, wherein the transition metal is selected from a group comprising ruthenium, cobalt, nickel, iron and rhodium, or any combination thereof, in which nanoparticles of the transition metal are dispersed in a liquid and the size of the nanoparticles of the transition metal is equal to 1-10 nm. Described is a method of preparing the described nanocatalyst, said method comprising the following steps: mixing and dispersing transition metal salts and polymer stabilisers in liquids, and reducing the transition metal salts with hydrogen in order to obtain a transition metal-based nanocatalyst, where temperature is equal to 100-200°C and concentration of the transition metal salts dissolved in the liquids is equal to 0.0014-0.014 mol/l. Described is a Fischer-Tropsch synthesis process which is carried out using the described nanocatalyst for converting carbon oxide and hydrogen to hydrocarbons.

EFFECT: obtaining an active nanocatalyst for the Fischer-Tropsch synthesis process.

17 cl, 1 tbl, 1 dwg, 10 ex

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RU 2 430 780 C2

Authors

Kou Juan

Jan Nin

Ksjao Chaoksjan

Kaj Zhipen

Li Jonvan

Dates

2011-10-10Published

2008-04-30Filed