FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing polymers with substituted cyclopropane groups in the backbone chain or side chains of general formula (1): . The method involves reaction of 1,2-polybutadiene with alkyldiazoacetate in the medium of an organic solvent in the presence of a catalyst. The catalyst used is copper (II) triflate - Cu(OTf)2, with molar ratio 1,2-polybutadiene: alkyldiazoacetate: catalyst equal to 1:0.5-1:0.01.
EFFECT: obtaining polymer products (1) with higher degree of functionalisation (conversion of unsaturated links to cyclopropane groups), with different molecular weight, which can be intentionally varied in a wide range of values.
3 cl, 7 ex, 1 tbl
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Authors
Dates
2012-04-10—Published
2010-11-17—Filed