FIELD: chemistry.
SUBSTANCE: invention relates to novel compounds of the N',N'-dialkylhydrazide class and can be used in copper hydrometallurgy. Para-tertbutylbenzoic acid N',N'-dialkylhydrazides of general formula tertC4H9C6H4CONHN(R)2 are obtained, where R is an aliphatic radical CnH2n+1 n=1-10. The compounds, preferably with number of carbon atoms per radical (n) from 6 to 10, are used as an extraction agent for copper (II) from ammonia solutions. Degree of extraction of copper (II) from solutions with ammonia content of up to 8 mol/l is equal to 96.5-99.4%.
EFFECT: compounds have high solubility in aliphatic hydrocarbon solvents.
2 cl, 3 tbl, 5 ex
Authors
Dates
2012-04-20—Published
2010-10-06—Filed