FIELD: chemistry.
SUBSTANCE: invention relates to heterogeneous catalysis, particularly a method of producing a catalyst for protium-deuterium isotopic exchange and ortho-para conversion of protium. The method involves obtaining silver nanoparticles from a reverse micellar solution followed by deposition on a Al2O3 support. Silver ions are reduced chemically. The reducing agent used is quercetin. Silver nanoparticles are obtained by preparing a reverse micellar solution of silver from 0.02-0.5 M solution of sodium bis(2-ethylhexyl)sulphosuccinate in a nonpolar solvent, 0.003-2.0 M aqueous solution of AgNO3 and 0.000075-0.0002 M quercetin solution. The obtained solution is treated with ultrasound to obtain a reverse micellar dispersion.
EFFECT: invention enables to obtain a catalyst for operation at temperatures maximally close to liquefaction temperatures of protium and deuterium.
1 dwg, 5 tbl, 4 ex
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METHOD OF PRODUCING CATALYST FOR PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
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Authors
Dates
2012-06-10—Published
2011-02-08—Filed