FIELD: chemistry.
SUBSTANCE: invention relates to heterogeneous catalysis, particularly to a method of producing a catalyst for protium-deuterium isotopic exchange and ortho-para conversion of protium. The method involves obtaining silver nanoparticles by radiochemical reduction of silver ions from a reverse micellar solution followed by deposition on an Al2O3 support, wherein the reverse micellar solution of silver is obtained from 0.02-0.5 M solution of bis(2-ethylhexyl) sodium sulphosuccinate in a non-polar solvent and 0.003-2.0 M aqueous solution of AgNO3; the prepared solution is treated with ultrasound until a reverse micellar dispersion is obtained, followed by dearation thereof, after which the suspension is exposed to γ-radiation of 60Co with a dose of 5-30 kGy.
EFFECT: invention enables to obtain a catalyst for operation at temperatures maximally close to liquefaction temperatures of protium and deuterium.
5 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING CATALYST FOR PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2482914C2 |
METHOD OF PRODUCING Ag/SiO CATALYST FOR HETEROGENEOUS CATALYSIS OF MOLECULAR HYDROGEN IN PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE REACTIONS AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2461412C1 |
METHOD OF PRODUCING CATALYST FOR PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2452570C1 |
METHOD OF PRODUCING CATALYST FOR PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2452569C1 |
METHOD OF PRODUCING CATALYST FOR PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE | 2011 |
|
RU2481155C2 |
METHOD OF OBTAINING CATALYST FOR ISOTOPIC PROTIUM-DEUTERIUM EXCHANGE | 2011 |
|
RU2490061C2 |
METHOD OF PRODUCING CATALYST FOR ORTHO-CONVERSION OF PROTIUM | 2011 |
|
RU2481891C2 |
METHOD OF PRODUCING Ag/SiO CATALYST FOR HETEROGENEOUS CATALYSIS OF MOLECULAR HYDROGEN IN PROTIUM-DEUTERIUM ISOTOPIC EXCHANGE REACTIONS AND ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2461413C1 |
METHOD OF PRODUCING CATALYST FOR ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2461425C1 |
METHOD OF PRODUCING CATALYST FOR ORTHO-PARA CONVERSION OF PROTIUM | 2011 |
|
RU2464096C1 |
Authors
Dates
2013-03-10—Published
2011-02-08—Filed