FIELD: chemistry.
SUBSTANCE: invention relates to versions of producing 2,3,3,3-tetrafluoropropene (1234yf). One of the versions involves (a) contacting 1,1,1-trifluoro-2,3-dichloropropane (243 db) with hydrogen fluoride (HF) in the presence of a zinc-chromium catalyst to form a compound of formula CF3CHFCH2X, where X is Cl or F; and (b) dehydrohalogenation of the compound of formula CF3CHFCH2X to form 1234yf.
EFFECT: use of the present method enables to obtain 2,3,3,3-tetrafluoropropene using only readily available starting materials and enables to avoid toxic by-products.
56 cl, 5 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING 1, 1,1-TRIFLUORO-2, 3-DICHLOROPROPANE | 2009 |
|
RU2476413C2 |
METHOD OF PRODUCING 2,3,3,3-TETRAFLUOROPROPENE | 2009 |
|
RU2466122C2 |
METHOD OF OBTAINING 2,3,3,3-TETRAFLUOROPROPENE | 2009 |
|
RU2523546C2 |
METHOD OF OBTAINING 2,3,3,3-TETRAFLUOROPROPENE | 2010 |
|
RU2547440C2 |
METHOD OF PRODUCING (HYDRO)FLUOROPROPENE | 2007 |
|
RU2466121C2 |
CATALYTIC GAS-PHASE FLUORINATION | 2011 |
|
RU2541541C1 |
METHOD OF PRODUCING 2,3,3,3-TETRAFLUOROPROPENE BY GAS-PHASE FLUORINATION OF PENTACHLOROPROPANE | 2011 |
|
RU2548902C2 |
CATALYTIC GAS-PHASE FLUORINATION | 2015 |
|
RU2654694C2 |
CATALYTIC GAS-PHASE FLUORINATION | 2011 |
|
RU2571415C2 |
METHOD OF SEPARATING FLUOROOLEFINS FROM HF BY LIQUID-LIQUID EXTRACTION | 2007 |
|
RU2448081C2 |
Authors
Dates
2012-10-10—Published
2009-04-09—Filed