FIELD: chemistry.
SUBSTANCE: method is carried out in at least two reactors connected in series, where 20-80 wt % of a first polymer is obtained in a suspension in a first reactor and 80-20 wt % second polymer is obtained in a suspension in a second reactor in the presence of the first polymer. One of the polymers is a low molecular weight polymer and the other is a high molecular weight polymer. A stream or suspension containing the obtained polymer is removed from the second reactor and transferred into a stripping reservoir operating under conditions such conditions as pressure and temperature through which at least 50 mol % of the liquid component of the suspension or the non-polymer component of the stream entering the stripping reservoir is removed from the stripping reservoir in vapour form. Stream or suspension concentration of components entering the stripping reservoir, having molecular weight lower than 50 g/mol, Clight products (mol %), satisfies the inequality Clight products<7+0.07(40-Tc)+4.4(Pc-0,8)-7(CH2/CEt), where Tc and Pc respectively denote temperature (°C) and manometric pressure (MPa) at the point where vapour from the stripping reservoir is condensed, and CH2 and CEt denote molar concentration of hydrogen and ethylene, respectively, in the stripping reservoir.
EFFECT: realising the process without need to recompress the liquid evaporated in the first stripping reservoir.
17 cl, 3 tbl, 3 ex
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METHOD FOR PREPARING COMPOSITION OF LINEAR LOW DENSITY POLYETHYLENE | 2003 |
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Authors
Dates
2012-12-10—Published
2008-08-29—Filed