FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 1,4-disubstituted [1.1.1b.1.1] pentipticenes , R = C=C-Ar; thienyl-2. The method involves reaction of pentipticene quinone with lithium derivatives of hetarenes and acetylenes, followed by aromatisation with a reducing agent. The method is characterised by that the reducing agent used is zinc dust in acetic acid.
EFFECT: use of the present method enables to increase output of the end product; the method is also simple and environmentally friendly and does not require use of expensive catalysts.
1 cl, 2 ex, 3 tbl
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Authors
Dates
2013-02-10—Published
2011-08-12—Filed