METHOD OF PRODUCING 1,4-DISUBSTITUTED [1.1.1.1.1] PENTIPTICENES Russian patent published in 2013 - IPC C07C13/62 C07C13/64 C07C13/70 C07C2/86 C07C1/20 C07D333/10 

Abstract RU 2474568 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing 1,4-disubstituted [1.1.1b.1.1] pentipticenes , R = C=C-Ar; thienyl-2. The method involves reaction of pentipticene quinone with lithium derivatives of hetarenes and acetylenes, followed by aromatisation with a reducing agent. The method is characterised by that the reducing agent used is zinc dust in acetic acid.

EFFECT: use of the present method enables to increase output of the end product; the method is also simple and environmentally friendly and does not require use of expensive catalysts.

1 cl, 2 ex, 3 tbl

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RU 2 474 568 C1

Authors

Zyrjanov Grigorij Vasil'Evich

Kovalev Igor' Sergeevich

Slepukhin Pavel Aleksandrovich

Kopchuk Dmitrij Sergeevich

Chupakhin Oleg Nikolaevich

Dates

2013-02-10Published

2011-08-12Filed