METHOD FOR ELECTROCHEMICAL DEPOSITION OF ACTINIDES Russian patent published in 2013 - IPC C25C1/22 

Abstract RU 2493295 C1

FIELD: chemistry.

SUBSTANCE: method involves oxidative dissolution of starting material in nitric acid and bringing acidity of the solution to 2-8 mol/l, extracting actinides from the obtained nitric acid solution using a solution of diphenyl(dibutyl)carbamoyl methylphosphine oxide in dichloroethane in the presence of 0.001-0.1 mol/l ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulphonyl)imide, wherein the obtained organometallic complex is further mixed with ionic liquid trihexyltetradecyl phosphonium hexafluorophosphate in form of a 1-10% solution in ethyl alcohol and cathode deposition of actinides is carried out at current density of 0.02-1.0 A/dm2.

EFFECT: invention increases efficiency, cost-effectiveness of deposition and provides high output of the desired component.

5 cl, 2 ex

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RU 2 493 295 C1

Authors

Novikov Aleksandr Pavlovich

Pribylova Galina Aleksandrovna

Smirnov Igor' Valentinovich

Dates

2013-09-20Published

2012-07-12Filed