FIELD: chemistry.
SUBSTANCE: invention relates to copolyamide, method of its obtaining, to polyamide-containing composition, application of polyamide and hypophosphorous acid or, at least, one of its salts. Copolyamide contains, at least, two links, corresponding to the following general formula: A/10.T. A is selected from the link, obtained from amino acid, link, obtained from lactam, and link, corresponding to the formula (Ca-diamine).(bibasic Cb-cycloaliphatic acid), where a stands for the number of diamine carbon atoms and b stands for the number of carbon atoms of bibasic acid. Each of a and b is in the range from 4 to 36. 10.T stands for the link, obtained as a result of polycondensatuon of 1,10-decandiamine and terephthalic acid. Copolyamide has polydispersion coefficient, measured by the method of gel permeation chromatography, denotes as lp, lower or equal to 3.5. Method of copolyamide obtaining lies in the following: stage of polycondensation of the following comonomers of monomer, resulting in A link, 1,10-decandiamine, and terephthalic acid, and optionally monomer, resulting in Z link, is carried out. polycondensation is carried out in presence of hypophosphorous acid or, at least, one of its salts in the amount in the range from 0.05 to 3.00 wt % with respect to the total weight of monomers. Application of hypophosphorous acid makes it possible to obtain polydispersion coefficient lower or equal to 3.5. Copolyamide is applied in form of powder, granulated products, monolayer structure, or, at least, one layer of multi-layer structure as additive and/or filling agent with improved thermal resistance. Such copolyamide is used in composition, which contains, at least, one additive, selected from filling agents, glass fibre, dyes, stabilisers, in particular UV-stabilisers, plasticisers, shock resistance modifiers surface active substances, pigments, bleaches, antioxidants, natural waxes, polyolefins and their mixtures.
EFFECT: invention makes it possible to obtain copolyamide with improved mechanical properties and shock resistance.
17 cl, 2 tbl, 2 ex
Authors
Dates
2014-04-10—Published
2009-08-06—Filed