FIELD: chemistry.
SUBSTANCE: disclosed is a method of producing bromodifluoromethyl(trimethyl)silane via bromation of difluoromethyl(trimethyl)silane while illuminating with an incandescent lamp in the temperature range of 50-85°C with molar ratio of difluoromethyl(trimethyl)silane to Br2 of 1:0.7-1. The end product is separated from the reaction mixture by distillation. Output is equal to 90-95% with conversion of the starting difluoromethyl(trimethyl)silane of 60-90%.
EFFECT: industrially suitable method of producing said compound with high output and easy separation of the end product.
3 ex
Title | Year | Author | Number |
---|---|---|---|
PROCESS FOR PREPARING $$$-BROMOSUBSTITUTED FATTY ACID ESTERS | 1993 |
|
RU2080317C1 |
METHOD OF SYNTHESIS OF 1,2-DIBROMO-1,1,2-TRIFLUOROETHANE OR 1,2-DIBROMO-1,1-DIFLUOROETHANE | 1990 |
|
RU1744933C |
PROCESS FOR PREPARING $$$-BROMOISOVALERIC ACID ETHYL ESTER | 1993 |
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RU2080318C1 |
METHOD FOR PRODUCING TRIMETHYL(TRIFLUOROMETHYL)SILANE | 2014 |
|
RU2550139C1 |
0 |
|
SU454205A1 | |
METHYL-(HEXAFLUOROALKYL)-DICHLOROSILANES FOR SYNTHESIS OF THERMO- AND OIL-GASOLINE-STABLE FLUORO-CONTAINING SILOXANE POLYMERS | 1995 |
|
RU2101286C1 |
METHOD OF PREPARING MONOBROMOXYLENES | 0 |
|
SU891619A1 |
0 |
|
SU455536A3 | |
0 |
|
SU545645A1 | |
0 |
|
SU539863A1 |
Authors
Dates
2014-09-20—Published
2013-05-27—Filed