ORGANOPHOSPHORUS COMPOUNDS, CATALYST SYSTEMS CONTAINING SAID COMPOUNDS, AND HYDROCYANATION METHOD USING SAID CATALYST SYSTEMS Russian patent published in 2014 - IPC C07F9/6571 C07B43/08 

Abstract RU 2530018 C2

FIELD: chemistry.

SUBSTANCE: invention relates to compounds of formula (I) and (II), a method for production thereof, metal-containing catalyst systems based on said compounds and a method for hydrocyanation in the presence of said catalyst systems. Compounds of formulae (I) and (II): where R1, R2, R3, R4, R6 and R7 denote H, C1-C12alkyl, an aromatic or cycloaliphatic ring, a carbonyl, alkoxycarbonyl or alkoxy radical, a halogen atom, a nitrile or haloalkyl group containing 1-12 carbon atoms, R5 and R8 denote an aliphatic radical containing 1-12 carbon atoms, an aromatic or cycloaliphatic ring, or multiple aromatic rings which are condensed or bonded with each other.

EFFECT: novel method of producing novel compounds and a catalyst system of formula M[Lf]t, where M denotes a transition metal, Lf denotes an organophosphorus ligand of formula (I) or (II), t is a number from 1 to 10, which can be used in a novel method for hydrocyanation of hydrocarbons.

14 cl, 12 ex, 1 tbl

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RU 2 530 018 C2

Authors

Mastrojanni Serdzho

Pringl Pol

Maldonado Ana

Rotenberg Gad

Mikhel' Igor'

Dates

2014-10-10Published

2010-08-31Filed