FIELD: chemistry.
SUBSTANCE: invention relates to compounds of formula (I) and (II), a method for production thereof, metal-containing catalyst systems based on said compounds and a method for hydrocyanation in the presence of said catalyst systems. Compounds of formulae (I) and (II): where R1, R2, R3, R4, R6 and R7 denote H, C1-C12alkyl, an aromatic or cycloaliphatic ring, a carbonyl, alkoxycarbonyl or alkoxy radical, a halogen atom, a nitrile or haloalkyl group containing 1-12 carbon atoms, R5 and R8 denote an aliphatic radical containing 1-12 carbon atoms, an aromatic or cycloaliphatic ring, or multiple aromatic rings which are condensed or bonded with each other.
EFFECT: novel method of producing novel compounds and a catalyst system of formula M[Lf]t, where M denotes a transition metal, Lf denotes an organophosphorus ligand of formula (I) or (II), t is a number from 1 to 10, which can be used in a novel method for hydrocyanation of hydrocarbons.
14 cl, 12 ex, 1 tbl
Authors
Dates
2014-10-10—Published
2010-08-31—Filed