FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing terephthalic acid from para-xylene, which includes preparing a mixture comprising para-xylene, a solvent, a bromine source, a catalyst and optionally ammonium acetate; and oxidising the para-xylene by bringing the mixture into contact with an oxidising agent in oxidative conditions to obtain a solid oxidation product, where said solid oxidation product comprises terephthalic acid, 4-carboxybenzaldehyde and para-toluic acid; where the solvent comprises a carboxylic acid having 1-7 carbon atoms, dialkylimidazole ionic liquid and optionally water, under the condition that the ratio of the ionic liquid to carboxylic acid in said solvent is in the range of 1:10 to 10:1 by weight; and where the catalyst contains at least one of the following elements: cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium and zirconium.
EFFECT: method enables to control content of different impurities in the solid oxidation product.
16 cl, 1 tbl, 9 ex
Title | Year | Author | Number |
---|---|---|---|
SOLID TEREPHTHALIC ACID COMPOSITION | 2011 |
|
RU2564409C2 |
METHOD OF OXIDISING ALKYLAROMATIC COMPOUNDS | 2011 |
|
RU2535996C2 |
METHOD OF PRODUCING TEREPHTHALIC ACID | 2011 |
|
RU2529902C2 |
METHOD OF PURIFYING TEREPHTHALIC ACID | 2011 |
|
RU2529903C2 |
MIXTURES, USED IN OXIDATION OF ALKYLAROMATIC COMPOUNDS | 2011 |
|
RU2540276C2 |
METHOD FOR OBTAINING TEREPHTHALIC ACID | 2012 |
|
RU2573564C2 |
METHOD OF OXIDISING ALKYL AROMATIC COMPOUNDS | 2011 |
|
RU2524947C2 |
METHOD OF OXIDISING ALKYL AROMATIC COMPOUNDS | 2012 |
|
RU2576319C2 |
METHOD FOR OXIDATION OF ALKYLAROMATIC COMPOUNDS | 2012 |
|
RU2572598C2 |
METHOD FOR ALKYLAROMATIC COMPOUND OXIDATION | 2012 |
|
RU2572627C2 |
Authors
Dates
2014-10-27—Published
2011-06-16—Filed