FIELD: chemistry.
SUBSTANCE: method includes the following steps: dissolving chromic anhydride in water; adding to the aqueous solution of chromic anhydride, a tertiary alcohol comprising at least 4 carbon atoms and a hydrocarbon solvent; reacting the alcohol and the chromic anhydride at a temperature ranging from 20°C to 40°C by subjecting the reaction medium to low pressure conditions in order to distil the water; recovering the catalyst in the form of a chromic acid ester in the solution of the hydrocarbon solvent.
EFFECT: method enables to obtain a stable solution of a catalyst for deperoxidation of alkylhydroperoxide with very good efficiency and high output.
15 cl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING ALKYLHYDROPEROXIDE | 2011 |
|
RU2530896C2 |
METHOD OF OXIDATING HYDROCARBONS WITH OXYGEN | 2010 |
|
RU2540857C2 |
METHOD OF PRODUCING ALCOHOL AND/OR KETONE | 2015 |
|
RU2697419C2 |
METHOD OF PREPARING MIXTURE OF CYCLOHEXANOL AND CYCLOHEXANONE | 2009 |
|
RU2409548C1 |
CONTINUOUS PROCESS FOR THE PRODUCTION OF PURIFIED CYCLOHEXANONE | 2014 |
|
RU2661867C2 |
METHOD OF PREPARING MIXTURE OF CYCLOHEXANOL AND CYCLOHEXANONE | 2009 |
|
RU2402520C1 |
CYCLOALKANE OXIDATION CATALYSTS AND METHOD TO PRODUCE ALCOHOLS AND KETONES | 2014 |
|
RU2652794C2 |
METHOD FOR OLEFIN EPOXIDATION WITH SIMULTANEOUS PRODUCTION OF NYLON PRECURSOR | 2005 |
|
RU2359964C2 |
PROCESS FOR STABILIZING TERT BUTYL CHROMATE | 0 |
|
SU923361A3 |
METHOD OF OXIDATION OF HYDROCARBONS | 2011 |
|
RU2531285C2 |
Authors
Dates
2015-02-10—Published
2010-11-18—Filed