FIELD: chemistry.
SUBSTANCE: invention relates to rare and radioactive element technologies and can be used to obtain concentrates of rare and rare-earth elements from monazite. The method of processing monazite concentrate includes treating the feed stock with a mixture of sulphuric acid and ammonium fluoride at 200-230°C for 30-40 min, purifying the obtained product from phosphate and fluoride products by sublimation, water leaching sulphates of rare-earth elements, neutralising the solution with barium chloride, selectively separating the thorium, uranium, iron and rare-earth product, wherein separation of the rare-earth product is carried out through a step of precipitating double salts of rare-earth elements with ammonium sulphate, followed by conversion into nitrates of rare-earth elements through a calcination step, dissolving in nitric acid and solvent refining from thorium impurities.
EFFECT: invention provides high degree of extraction and purity of the rare-earth product.
3 cl, 2 dwg, 3 ex
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Authors
Dates
2015-04-27—Published
2013-10-14—Filed