PESTICIDE COMPOSITIONS Russian patent published in 2015 - IPC C07D417/04 C07D417/14 A01P7/04 A01N43/40 A01N43/28 

FIELD: chemistry.

SUBSTANCE: invention relates to a compound of formula:

I

where (a) X is N or CR8; (b) R1 is H, F, Cl, Br; (c) R2 is H; (d) R3 is H, F, Cl, Br; (e) R4 is H, F, Cl, Br, I, CN, substituted or unsubstituted C₁-C₆alkyl, substituted or unsubstituted C₂-C₆alkenyl, substituted or unsubstituted C₆-aryl, SR9, where each of said R4, which is substituted, contains one or more substitutes selected from F, Cl, Br; (f) R5 is H, substituted or unsubstituted C₁-C₆alkyl, substituted or unsubstituted C₂-C₆alkenyl, C(=X1)R9, C(=X1)OR9, C₁-C₆alkylC₆-aryl (where the aryl can be substituted or unsubstituted), R9X2C(=X1)R9, R9X2R9, C(=O)(C₁-C₆alkyl)S(O)_n(C₁-C₆alkyl), C(=O)(C₁-C₆alkyl)C(=O)O(C₁-C₆alkyl), (C₂-C₆alkenyl)C(=O)O(C₁-C₆alkyl), SR9, R9S(O)_nR9; where each of said R5, which is substituted, contains one substitute selected from F, Cl, Br, C₃-C₁₀cycloalkyl, OR9, optionally, R5 and R7 can be bonded to form a C₃ cyclic system; (g) R6 is O, S, NR9; (h) R7 is substituted or unsubstituted C₁-C₆alkyl, substituted or unsubstituted C₂-C₆alkenyl, substituted or unsubstituted C₁-C₆alkoxy, substituted or unsubstituted C₃-C₁₀cycloalkyl, substituted or unsubstituted C₆-aryl, substituted or unsubstituted C₁-C₂₀heterocyclyl, selected from thiazole, oxazole, isothiazole, thiophene, pyrroidine, furan, tetrahydrothiophene, pyridazine, piperdine, pyrazole, OR9, OR9S(O)_nR9, C(=X1)R9, R9C(=X1)OR9, N(R9)₂, N(R9)(R9S(O)_nR9), SR9, R9S(O)_nR9, C₁-C₆alkylC₁-C₂₀heterocyclyl (where the heterocyclyl is selected from triazole and pyrazole), C₁-C₆alkylS(=N-CN)(C₁-C₆alkyl), C₁-C₆alkylS(O)(=N-CN)(C₁-C₆alkyl), C₁-C₆alkylNH(C(=O)OC₁-C₆alkyl), C₁-C₆ alkylC(=O)OC₁-C₆alkyl, C₁-C₆alkyl(C₆-aryl)NH(C(=O)OC₁-C₆alkyl), C₁-C₆alkyl(S-C₁-C₆alkyl)NH(C(=O)OC₁-C₆alkyl), C₁-C₆alkyl(S-C₁-C₆alkyl-C₆-aryl)NH(C(=O)OC₁-C₆alkyl), C₁-C₆ alkyl(NHC(=O)OC₁-C₆alkylC₆-aryl)NH(C(=O)OC₁-C₆alkyl), C₁-C₆alkyl(OC₁-C₆alkylC₆-C₂₀aryl)NH(C(=O)OC₁-C₆alkyl), C₁-C₆alkylNH(C₁-C₆alkyl)(C(=O)OC₁-C₆alkyl), C₁-C₆alkylNH(C₁-C₆alkyl), C₁-C₆alkylN(C₁-C₆ alkyl)(S(O)_nC₁-C₆alkyl), C₁-C₆alkylN(C₁-C₆alkyl)(S(O)_nC₁-C₆alkenylC₆-aryl), C₁-C₆alkylN(C₁-C₆alkyl)(C(=O)C₁-C₂₀heterocyclyl) (where the heterocyclyl is selected from pyrazole or thiophene), C₁-C₆alkylN(C₁-C₆alkyl)(C(=O)OC₁-C₆alkylC₆-aryl), NH(C₁-C₆alkylS(O)_nC₁-C₆alkyl), where each of said R7, which is substituted, contains one or more substitutes selected from F, Cl, Br, C₁-C₆ alkyl, C₃-C₁₀ cycloalkyl, C(=X1)R9, C(=X1)OR9, =X2, S(=X2)_nR9; (i) R8 is H, F, Cl, Br, I, CN, unsubstituted C₁-C₆alkoxy, C(=X)OR9, S(O)_nR9; (j) R9 (each independently) is H, substituted or unsubstituted C₁-C₆alkyl, substituted or unsubstituted C₂-C₆alkenyl, substituted or unsubstituted C₁-C₆alkoxy, substituted or unsubstituted C₂-C₆alkenyloxy, substituted or unsubstituted C₃-C₁₀cycloalkyl, substituted or unsubstituted C₆-aryl, where each of said R9, which is substituted, contains one or more substitutes selected from F, Cl, Br, C₁-C₆alkyl, OC₁-C₆ alkyl, C₆-aryl; (k) n equals 0, 1 or 2; (l) X1 is (each independently) O; (m) X2 is (each independently) O. The invention also relates to versions of the compound of formula (I). Compounds of formula (I) are intended for pest control and seed treatment.

EFFECT: thiazole derivatives for pest control.

12 cl, 2 tbl, 83 ex