FIELD: chemistry.
SUBSTANCE: group of inventions relates to compounds with pesticidal activity and includes a compound of formula one, its stereoisomers and tautomers, a composition for controlling insects based thereon and a method of controlling insects. In the formula, one R1 is H; R2, R4 is selected from the group consisting of H, F, Cl, Br, I, CN, (C1-C6)alkyl and (C1-C6)haloalkyl; R3 is selected from the group consisting of H, F, Cl, Br, I, (C1-C6)alkyl and (C1-C6)haloalkyl; R5, R6, R9 are H; R7 and R8 are selected from the group consisting of F and Cl; Q1 and Q2 are selected from the group consisting of O and S; R10 is selected from the group consisting of H and (C1-C6)alkyl; R11 is selected from the group consisting of H, F, Cl, Br, I and (C1-C6)alkyl; R12 is selected from a group consisting of H, F, Cl, Br and I; X1 is CR13, where R13 is selected from the group consisting of H, F, Cl, Br, I, CN and (C1-C6)alkyl; X2 is CR14, where R14 is selected from the group consisting of H, F, Cl, Br, I, CN and (C1-C6)alkoxy; X3 is selected from the group consisting of N(R15) (substituted or unsubstituted heterocyclyl) and a substituted or unsubstituted heterocyclyl, wherein said heterocyclyl is selected from the group consisting of benzoimidazolyl, benzothiozolyl, benzothiophenyl, benzoxazolyl, indazolyl, indolyl, indolinyl, isoindolyl, oxazolyl, pyrazinyl, pyrazolyl, pyridazinyl, pyridyl, pyrimidinyl, pyrrolopyridinyl, quinolinyl, 1,2,3,4-tetrahydroquinolinyl, tetrazolyl, thiadiazolyl, thiazolyl, thienyl, triazinyl, triazolyl and pyrimidine-2,4(1H,3H)-dionyl; R15 is selected from the group consisting of H and (C1-C6)alkyl; said substituted heterocyclyl has one or more substituents selected from the group consisting of F, Cl, Br, I, H, CN, NHOH, NO2, (C1-C6)alkoxy, (C1-C6)alkyl, (C1-C6)alkylphenyl, (C1-C6)haloalkoxy, (C1-C6)haloalkyl, (C2-C6)alkenyl, (C2-C6)haloalkenyl, C(O)(C1-C6)alkyl, C(O)NH(C1-C6)alkyl, C(O)NH-phenyl, C(O)O(C1-C6)alkyl, NH(C1-C6)alkyl, NH(C1-C6)alkylphenyl, NH2, NHC(O)(C1-C6)alkyl, NHC(O)(C1-C6)alkylphenyl, NHC(O)(C1-C6)haloalkyl, NHC(O)(C2-C6)alkenyl, NH-C(O)O(C1-C6)alkyl, phenyl, pyridinyl, S(C1-C6)alkyl, S(C1-C6)haloalkyl, thiazolyl, thienyl and triazolyl; wherein each of alkoxy, alkyl, haloalkoxy, haloalkyl, alkenyl, haloalkenyl, phenyl, pyrazolyl, pyridinyl, thiazolyl, thienyl and triazolyl can be optionally substituted with one or more substitutes selected from the group consisting of F, Cl, Br, I, CN, OH, NH2, NO2, oxo, (C1-C6)alkyl, (C1-C6)alkyl, (C1-C6)alkoxy, C(O)O-(C1-C6)alkyl, (C1-C6)haloalkoxy, (C1-C6)haloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl and (C3-C6)halocycloalkyl.
EFFECT: disclosed are compounds which are useful as pesticides, and intermediate compounds, compositions and methods related thereto.
7 cl, 8 tbl, 110 ex
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