FIELD: chemistry.
SUBSTANCE: invention relates to chemical industry and can be used in production of lithium compounds. The method comprises three steps. The first step includes thermal decomposition of limestone to obtain unslaked lime (CaO) and carbon dioxide gas. At the second step the obtained lithium-containing solution is treated with a gaseous mixture of NH3 and CO2, taken in molar ratio of 2:1, to obtain a solid phase of the desired product Li2CO3 and a mother solution containing an ammonium salt (NH4Cl, or NH4NO3, or (NH4)2SO4). The third step includes calcination of the ammonium salt solution to reproduce ammonia, which is returned to the Li2CO3 precipitation operation.
EFFECT: invention enables to use cheap and readily available material when producing cathode material for lithium-ion batteries.
6 cl, 6 dwg, 7 ex
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Authors
Dates
2015-08-20—Published
2013-11-19—Filed