FIELD: chemistry.
SUBSTANCE: method includes consecutive procedures for preparing a flow sample by cooling a sample to 10-50°C and reducing pressure to atmospheric pressure, conductometric measurement of electroconductivity (χt) and temperature (t) of a straight sample, passing the sample through an H-cationite column, conductometric measurement of electroconductivity (χt H) and temperature (tH) of an H-cationated sample, reducing the measured electroconductivity values to temperature of 25°C (χ, χH), checking accuracy, determining the difference between electroconductivity values of the straight and H-cationated samples (χ-χH) and calculating the pH value by solving a system of equations of ionic equlibria of the aqueous solution.
EFFECT: providing a method of determining pH of low-buffer maximally diluted condensate-type aqueous solutions, which provides accurate and fast determination of pH, and is cost-effective and easy to use.
2 tbl, 2 dwg
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Authors
Dates
2016-01-20—Published
2014-08-14—Filed