FIELD: chemistry.
SUBSTANCE: invention relates to new derivatives of tris(2-hydroxyphenyl)-methane having the general formula (I), with surface-active properties, where
R are independently of one another, 0 to 4 unbranched or branched aliphatic hydrocarbon radicals having 1 to 6 carbon atoms per phenyl ring,
R1 is a radical selected from the group consisting of hydrogen, hydroxyl and hydrocarbon groups having 1 to 6 carbon atoms,
R2 are independently of one another, radicals of the general formula (III) -(R5-O-)n-R6-X, where n is a number from 1 to 50,
and where the radicals R5 independently of one another, are selected from the group consisting of radicals R7, R8 and R9: ,
where R6, X, R10 and R11 independently of one another, have the following meaning:
R6 is a single bond or an alkylene group having 1 to 10 carbon atoms,
X is hydrogen or a hydrophilic group, where the hydrophilic group is an acidic group or a radical which comprises at least one OH group,
R10 is hydrogen or an aliphatic hydrocarbon radical having 1 to 6 carbon atoms,
R11 is a group -(R5-O-)m-R6-X, where m is a number from 0 to 50,
and where the total number z of all groups R5 in a radical R2 is 1 to 50 with the proviso that z is a number from 2 to 50, if at least one X is hydrogen.
EFFECT: preparation of derivatives of tris(2-hydroxyphenyl)methane.
14 cl, 6 dwg, 4 tbl, 6 ex
Authors
Dates
2016-05-20—Published
2011-05-18—Filed