FIELD: petrochemical industry.
SUBSTANCE: invention relates to petrochemical synthesis, particularly, to heterogeneous catalysts for converting alkyl formates (decarbonylation reaction) to corresponding alcohols. Invention relates to a catalyst for splitting alkyl formates, containing: zinc oxide 87.90-99.10 wt%, aluminium oxide 0.24-1.80 wt%, calcium oxide 0.35-5.60 wt%, magnesium oxide 0.10-3.30 wt%, impurities of sulphur - not more than 0.15 wt%, other components - not more than 1.25 wt%; graphite - balance, and also a method of splitting alkyl formates in atmosphere of hydrogen in presence of catalyst according to invention.
EFFECT: technical result consists in providing more complete conversion of alkyl formates to corresponding alcohols, increase in end product yield, reduced output of toxic products, such as methanol, increased amount of processed raw material per unit time, as well as low process temperature.
23 cl, 3 dwg, 6 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
BUTANOL-BUTYL FORMATE FRACTION PROCESSING METHOD | 2005 |
|
RU2284313C1 |
METHOD OF PROCESSING BUTANOL-BUTYL FORMATE FRACTION | 2011 |
|
RU2454392C1 |
PROCESS FOR PURIFYING OXYGEN-CONTAINING ORGANIC PRODUCTS OF HYDROFORMYLATION FROM ALKYL FORMIATES | 0 |
|
SU1133255A1 |
METHOD OF ACTIVATING COPPER-ZINC-CHROMIUM CATALYST FOR HYDROGENATION OF ALDEHYDES | 1999 |
|
RU2148433C1 |
METHOD FOR SEPARATING PRODUCTS OF PROPYLENE HYDROFORMYLATION | 2004 |
|
RU2254323C1 |
PROCESS FOR PREPARING BUTANOLS | 0 |
|
SU1087510A1 |
BUTYL ALCOHOLS PRODUCTION PROCESS | 2004 |
|
RU2259345C1 |
METHOD OF SEPARATING ALIPHATIC ALCOHOLS FROM PROPYLENE HYDROFORMILATION PRODUCTS | 0 |
|
SU1684272A1 |
METHOD OF ORGANIC WASTE PROCESSING | 2002 |
|
RU2217199C1 |
OBTAINING BRANCHED ALIPHATIC ALCOHOLS USING JOINED TECHNOLOGICAL FLOWS OF HYDRATION INSTALLATION AND INSTALLATION FOR DEHYDRATION-ISOMERISATION | 2004 |
|
RU2352551C2 |
Authors
Dates
2016-06-10—Published
2014-12-30—Filed