FIELD: technological processes.
SUBSTANCE: invention relates to a method of producing alkyl esters of fatty acids (AEFA) and can be used in petrochemical, fuel and other industries. Method of producing alkyl esters of fatty acids is carried out by re-esterification reaction of vegetable oil with an alkylating agent methanol in supercritical carbon dioxide medium while heating in presence of immobilised lipase, where matrix of immobilised lipase used is magnetically separated iron-containing nanoparticles with modified 3-(aminopropyl)-triethoxysilane surface, molar ratio of vegetable oil to methanol ranges from 1:3 to 1:6, re-esterification reaction is carried out at temperature from 40 to 60 °C and pressure of carbon dioxide from 10.0 to 20.0 MPa for 3-5 hours in a neutral medium.
EFFECT: technical result is improvement of manufacturability, efficiency and stability of selective production of AEFA.
1 cl, 1 tbl, 1 ex
Title | Year | Author | Number |
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METHOD OF VEGETABLE OIL PROCESSING | 2007 |
|
RU2365625C1 |
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METHOD OF PRODUCING CARBOXYLIC ALKYL ESTERS | 2006 |
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RU2425024C2 |
REFINING OF OIL COMPOSITION | 1995 |
|
RU2151788C1 |
METHOD OF PRODUCING BIODIESEL FUEL | 2008 |
|
RU2412236C2 |
METHOD FOR ESTERIFICATION AND TRANSESTERIFICATION OF FAT RAW MATERIALS | 2020 |
|
RU2751698C1 |
Authors
Dates
2016-11-10—Published
2015-07-08—Filed