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2 602 263

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IPC

C07F3/06(2006-01-01)

C07C211/65(2006-01-01)

C07C211/44(2006-01-01)

C09K11/54(2006-01-01)

C09K11/06(2006-01-01)

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Application

2015137127/05, 2015-08-31

(24)

Start date

2015-08-31

(22)

Actual filing date

2015-08-31

(45)

Published

2016-11-10

(72)

Inventor

Burlov Anatolij SergeevichVlasenko Valerij GrigorevichMakarova Nadezhda IvanovnaGarnovskij Dmitrij AleksandrovichMetelitsa Anatolij ViktorovichMinkin Vladimir Isaakovich

(73)

Holder

Federalnoe Gosudarstvennoe Avtonomnoe Obrazovatelnoe Uchrezhdenie Vysshego Obrazovanija Federalnyj Universitet"

BIS-[2-(SUBSTITUTED BENZYLIDENE)-3',4'-DIMETHOXYPHENYLETHYLIMINATE]ZINC(II), HAVING LUMINESCENT ACTIVITY Russian patent published in 2016 - IPC C07F3/06 C07C211/65 C07C211/44 C09K11/54 C09K11/06

Abstract RU 2602263 C1

FIELD: chemistry.

SUBSTANCE: invention relates to novel compounds metal-chalate-bidentate azomethine ligands of 2-N-tosylaminobenzaldehyde and 2-hydroxybenzaldehyde and aralkylamines, specifically to bis-[2-(N-tosylaminobenzylidene)-3′,4′-dimethoxyphenylethyliminate]zinc(II) and bis-[2-(hydroxybenzylidene)-3′,4-dimethoxyphenylethyliminate]zinc(II) of formula I:

where X=NTs (a), X=O (b), Ts=-SO₂-C₆H₄-CH₃-p. Novel complexes of zinc - bis-[2-(N-tosylaminobenzylidene)-3′,4′-dimethoxyphenylethyliminate]zinc(II) and bis-[2-(hydroxybenzylidene)-3′,4′-dimethoxyphenylethyliminate]zinc(II), exhibit photoluminescent properties in violet and blue spectrum λ_fl=427 nm and λ_fl=442 nm with quantum fluorescence output 0.33 and 0.36 respectively and have thermal stability.

EFFECT: compounds can be used in designing organic light-emitting diodes (OLED) of white and visible light as electroluminescent layers.

1 cl, 1 dwg, 5 ex

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RU 2 602 263 C1

Authors

Burlov Anatolij Sergeevich

Vlasenko Valerij Grigorevich

Makarova Nadezhda Ivanovna

Garnovskij Dmitrij Aleksandrovich

Metelitsa Anatolij Viktorovich

Minkin Vladimir Isaakovich

Dates

2016-11-10—Published

2015-08-31—Filed