IMPROVED CATALYST FOR OXIDATION OF N-BUTANE TO MALEIC ANHYDRIDE Russian patent published in 2016 - IPC B01J27/198 B01J27/199 B01J37/02 B01J35/00 C07C51/215 

Abstract RU 2605550 C2

FIELD: chemistry.

SUBSTANCE: invention relates to an improved catalyst for oxidation of n-butane into maleic anhydride. Method of producing promoted VPO catalyst, which contains mixed oxides of vanadium and phosphorus and is promoted with at least one of niobium, cobalt, iron, zinc, molybdenum or titanium. Method includes steps of: (i) obtaining a VPO catalyst, containing more than 80 wt% vanadyl pyrophosphate and less than 5 wt% vanadyl phosphate, (ii) bringing VPO catalyst into contact with a solution, containing compound which serves as a source of at least one metal, selected from a group consisting of niobium, cobalt, iron, zinc, molybdenum or titanium, for formation of a metal-impregnated VPO catalyst, and (iii) drying metal-impregnated VPO catalyst to form promoted VPO catalyst. Disclosed is a version of method.

EFFECT: technical result is catalyst provides high conversion of n-butane and output of maleic anhydride.

17 cl, 1 tbl, 23 ex

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RU 2 605 550 C2

Authors

Haddad Muin S.

Gustaferro Robert A.

Dates

2016-12-20Published

2012-10-22Filed