FIELD: chemistry.
SUBSTANCE: invention relates to a method of making a catalyst composition, suitable for hydroprocessing o hydrocarbon feedstock. Method involves preparation of a support particle, that is an inorganic oxide material; impregnating said support particle with a first aqueous impregnation solution comprising a first Group VIII metal component, a first Group VIB metal component and a first phosphorous component, to thereby provide a metal impregnated support; calcining said metal impregnated support to provide a base catalyst, comprising type I active sites and said first phosphorous component; impregnating said base catalyst with a second aqueous impregnation solution comprising a second Group VIII component, a second Group VIB component and a second phosphorous component to thereby provide a metal impregnated base catalyst; drying said metal impregnated base catalyst under non-calcination conditions that are controlled so as to provide a dried intermediate comprising type II active sites and said second phosphorous component; and sulphiding said dried intermediate, without a prior calcination thereof. Disclosed also is a version of method, catalyst composition, method of hydroprocessing hydrocarbon feedstock and a composition suitable in hydroprocessing hydrocarbon feedstock.
EFFECT: method enables optimisation and control of relative ratio of different types of catalytically active centres in catalyst composition to produce certain required results and improved catalytic properties.
28 cl, 1 dwg, 1 tbl, 5 ex
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Authors
Dates
2017-02-17—Published
2012-06-20—Filed