FIELD: chemistry.
SUBSTANCE: method of processing waste potassium bifluoride comprises its grinding, treatment with sulfuric acid with concentration of 95-100% in a molar ratio of sulfuric acid: potassium bifluoride as 1:1.02. The resulting mixture is heated to 130-150°C and held for 3-4 hours. The resulting hydrogen fluoride is stripped. Hydrogen fluoride absorption by water to obtain hydrofluoric acid is possible. Neutralisation of mass remaining after stripping of the hydrogen fluoride is carried out using aqueous solution of hydroxide or potassium carbonate to pH 7-7.5.
EFFECT: resulting potassium sulfate is dried The invention enables to process waste potassium bifluoride having high acidity and toxicity into commodity products - hydrogen fluoride and/or hydrofluoric acid and clear potassium sulfate.
5 tbl, 4 ex
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Authors
Dates
2017-04-18—Published
2016-04-20—Filed