FIELD: chemistry.
SUBSTANCE: invention relates to the macromonomer of Formula 1, where the values for the R1, R2, m, n, are given in the claims that are used to prepare the cement additive. Also a process of preparing the macromonomer cement additive comprising a copolymer of a polycarboxylic acid derived from the macromonomer and the layered double hydroxide and a method for its preparation is disclosed. The copolymer based on the polycarboxylic acid comprises (a) a structural unit derived from the macromonomer compound represented by the formula 1 below and (b) a structural unit derived from the acrylic monomer represented by the formula 4 wherein the values for the R3, M1 are given in the claims. Formula 1: CH2=CR1-(CH2)m-O-(CH2CH2O)n-OCO-R2-COOH, Formula 4: CH2=CR3-CO-M1.
EFFECT: cement admixture has excellent dispersibility, workability and corrosion resistance.
25 cl, 4 dwg, 7 tbl, 14 ex
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Authors
Dates
2017-07-07—Published
2014-04-18—Filed