FIELD: chemistry.
SUBSTANCE: invention relates to a process of the preparation of a product of methanol, product H2 and a CO product from a synthesis gas containing H2 and CO, in particular from the exhaust gas of acetylene production. The method includes separating a syngas stream into first and second partial synthesis gas streams where only the CO present in the first partial synthesis gas stream is converted to CO2 and H2 using steam, washing the first partial synthesis gas stream and a portion of the second partial synthesis gas stream, each in a separate column with an amine-containing washing agent, in particular for washing from CO2, wherein in particular the washing agent is regenerated in a common column, wherein the methanol product stream is formed from one portion of the washed converted first partial synthesis gas stream and/or another portion of the unconverted second syngas stream so that the ratio (H2-CO2)/(CO+CO2), which is required for the synthesis of methanol, is regulated in the methanol product stream, in particular in the range of 2.0 to 2.1, where the washed one part of the second unconverted partial synthesis gas stream is used to produce the CO product stream and the H2 product stream and where the other portion of the washed first partial synthesis stream is synthesized, gas is used to produce the product stream H2.
EFFECT: invention provides an efficient and economical preparation of three methanol products, H2 and CO from a synthesis gas containing H2 and CO.
10 cl, 1 dwg
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Authors
Dates
2017-08-08—Published
2013-05-08—Filed