DEHYDRATION OF WATER-CONTAINING FORMALDEHYDE SOURCE AND METHOD FOR PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACID ESTER Russian patent published in 2017 - IPC C07C45/79 B01D61/36 C07C47/58 C07C67/343 C07C69/54 

Abstract RU 2632869 C2

FIELD: chemistry.

SUBSTANCE: method for water-containing source formaldehyde dehydration involves formaldehyde source contacting with a zeolite membrane in a manner effective to recover at least a portion of water from the formaldehyde source. At that, the water-containing formaldehyde source contains a separation intensifier with relative static permittivity between 2.5 and 20 at 20°C and at atmospheric pressure, and the water-containing formaldehyde source additionally contains methanol. The invention also relates to a method for ethylenically unsaturated carboxylic acid ester production, which comprises contacting of the dehydrated formaldehyde source obtained by the above method with a carboxylic acid ester in the presence of a catalyst.

EFFECT: dehydration method allows to separate water from the formaldehyde source with high efficiency.

15 cl, 2 dwg, 2 tbl, 21 ex

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RU 2 632 869 C2

Authors

Khimeno Josiyuki

Ooyati Ken

Kondo Masakhide

Dates

2017-10-11Published

2013-02-18Filed