FIELD: chemistry.
SUBSTANCE: method for water-containing source formaldehyde dehydration involves formaldehyde source contacting with a zeolite membrane in a manner effective to recover at least a portion of water from the formaldehyde source. At that, the water-containing formaldehyde source contains a separation intensifier with relative static permittivity between 2.5 and 20 at 20°C and at atmospheric pressure, and the water-containing formaldehyde source additionally contains methanol. The invention also relates to a method for ethylenically unsaturated carboxylic acid ester production, which comprises contacting of the dehydrated formaldehyde source obtained by the above method with a carboxylic acid ester in the presence of a catalyst.
EFFECT: dehydration method allows to separate water from the formaldehyde source with high efficiency.
15 cl, 2 dwg, 2 tbl, 21 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF MANUFACTURING COMPOSITE POLYMER PERVAPORATION MEMBRANES | 1997 |
|
RU2129910C1 |
DEHYDROGENATION OF MIXED ALCOHOLS | 2006 |
|
RU2412141C2 |
TREATMENT OF FORMALDEHYDE-CONTAINING MIXTURES | 1998 |
|
RU2217413C2 |
METHOD OF METHYL METHACRYLATE PURIFICATION | 2009 |
|
RU2523228C2 |
METHOD OF POLYMERIC MULTILAYER PERVAPORATION MEMBRANE MAKING | 1998 |
|
RU2166984C2 |
METHOD OF OBTAINING ETHYLENE-UNSATURATED CARBOXYLIC ACIDS OR THEIR COMPLEX ETHERS AND CATALYST FOR THIS | 2013 |
|
RU2621687C2 |
MIXED OXIDE BASED CATALYST AND METHOD OF PRODUCING ETHYLENICALLY UNSATURATED CARBOXYLIC ACIDS OR ESTERS | 2011 |
|
RU2579516C2 |
METHOD FOR PREPARING N-PHOSPHONOMETHYLGLYCINE | 2002 |
|
RU2274641C2 |
METHOD FOR CARBONYLATION OF ALKYL ETHERS | 2006 |
|
RU2411232C2 |
METHOD OF PRODUCING SUGAR SOLUTION | 2012 |
|
RU2583689C2 |
Authors
Dates
2017-10-11—Published
2013-02-18—Filed