FIELD: chemistry.
SUBSTANCE: invention relates to a method of preparing a catalyst for hydrofining petroleum fractions, comprising impregnating a support with a solution of compounds of Group VI metals and nickel oxycarbonate or cobalt, from a co-impregnating solution containing a phosphorus-molybdenum or phosphorus-tungsten heteropoly complex and nickel or cobalt metal ions Me2+. Carrier is a composite material consisting of a mixture of ZnO and Al2O3 oxides composition, obtained by mixing Zn and Al hydroxides, peptising them with a solution of organic acid (ice CH3COOH), extrusion, drying at 60–80–100 °C, calcination at final temperature of 550 °C. Invention also relates to a catalyst for hydrofining petroleum fractions, obtained by said method, containing cobalt oxide or nickel oxide, phosphorus-molybdenum or phosphorus-tungsten heteropolycomplex, with the following content of components, wt. %: CoO or NiO 3.0–5.0; MoO3 14.0–20.0; WO3 6.0–20.0; P2O5 0.3–0.8; ZnO from 0.1 to 10.0; aluminium oxide - balance.
EFFECT: technical result is higher catalytic activity of hydrotreating catalyst.
6 cl, 1 tbl, 6 ex
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Authors
Dates
2019-09-19—Published
2016-10-20—Filed