FIELD: chemistry.
SUBSTANCE: invention relates to a catalyst for combined hydrofining of a mixture of vegetable and petroleum hydrocarbon material. This catalyst includes cobalt, nickel, molybdenum and aluminium oxide, wherein it contains in a state calcined at 550 °C: Mo - 9.0–15.0 wt. %, Co - 0.5–3.5 wt. % and Ni is 0.5–3.5 wt. %; the rest is a porous support with carbon content of 0–5 wt. %; catalyst has specific surface area of 100–250 m2/g, specific pore volume of 0.3–1.1 cm3/g, average pore diameter of 4.0–10.0 nm. Method of preparing said catalyst comprises impregnating a carrier on a moisture capacity followed by drying, wherein the vacuum-containing support containing aluminium oxide is impregnated once with an aqueous solution of precursors of active components, containing molybdenum heteropolyacid, nickel or cobalt complexonate with carboxylic acid.
EFFECT: technical result is increased activity and stability of catalyst in process of combined hydrofining mixture of vegetable and petroleum hydrocarbon material.
5 cl, 2 tbl, 10 ex
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Authors
Dates
2019-12-02—Published
2017-12-28—Filed