FIELD: technological processes.
SUBSTANCE: invention relates to polymerization processes, particularly to the development of reactive photopolymerizable compositions. Thermo- and heat-resistant polymer based on bis-(1-halomethyl-2-allyloxy-ethoxy)-(1-halomethyl-2-phenoxyethoxy) phosphines is obtained by radical polymerization of bis-(1-halomethyl-2-allyloxy-ethoxy)-(1-halomethyl-2-phenoxy-ethoxy] phosphine in presence of 0.5 wt% photoinitiator. Polymerization initiator used is a photoinitiator of bisphenyl(2,4,6-trimethylbenzoyl)phosphine oxide. Polymerization is carried out in the presence of ultraviolet radiation.
EFFECT: simple method of producing thermo- and heat-resistant polymers based on bis-(1-halomethyl-2-allyloxy-ethoxy)-(1-halomethyl-2-phenoxyethoxy) phosphines, high thermal stability of polymers, as well as wider field of use thereof.
1 cl, 2 tbl, 2 ex
Authors
Dates
2020-01-24—Published
2019-06-03—Filed