FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing thermo- and heat-resistant polymers based on bis-(1-halomethyl-2-methacryloxyethoxy)-(1-halomethyl-2-phenoxyethoxy)phosphines. Proposed method consists in radical polymerization of bis-(1-halomethyl-2-methacryloxyethoxy)-(1-halomethyl-2-phenoxyethoxy)phosphine in presence of polymerization initiator. Initiator of polymerization is a photoinitiator – bisphenyl(2,4,6-trimethylbenzoyl)phosphine oxide. Initiator is taken in amount of 0.5 wt% of monomer. Polymerization is carried out in the presence of ultraviolet radiation.
EFFECT: simple method of producing thermo- and heat-resistant polymers based on bis-(1-halomethyl-2-methacryloxyethoxy)-(1-halomethyl-2-phenoxyethoxy)phosphines, high thermal stability of polymers, as well as wider field of use thereof.
1 cl, 2 tbl, 2 ex
Authors
Dates
2020-03-24—Published
2019-06-03—Filed