FIELD: radiochemical technologies.
SUBSTANCE: invention relates to radiochemical technologies, namely to methods for dissolution of substandard solid-propellant MOX fuel composition, which is a mixture of uranium and plutonium dioxides or uranium-plutonium dioxide, sintered. The method for dissolving substandard tableted products of MOX fuel production includes the joint dissolution of uranium and plutonium in concentrated nitric acid. The substandard material is a mixture of uranium and plutonium dioxides or uranium-plutonium dioxide. It is transferred to a finely dispersed state, then treated with 250-440 g/l with a solution of nitric acid at a ratio of the mass of substandard material to the volume of nitric acid in the range of 1:(5÷7) with periodic introduction of a concentrated solution of hydrogen peroxide at a temperature of 40-60°C.
EFFECT: allows dissolving at least 98% of substandard tableted products produced by MOX fuel with obtaining a combined uranium-plutonium nitrate solution, which does not contain additionally introduced metal ions that are not part of the MOX fuel, as well as corrosive components.
5 cl, 1 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR DISSOLVING OFF-GRADE PELLETIZED PRODUCTS OF MOX-FUEL PRODUCTION | 2019 |
|
RU2704310C1 |
METHOD FOR REGENERATION OF SILVER FROM ACTINOID-CONTAINING NITRIC-ACID SOLUTION | 2020 |
|
RU2753358C2 |
METHOD OF DISSOLVING PLUTONIUM DIOXIDE, MOX-FUEL SCRAP AND EXTRACTING AMERICIUM | 2020 |
|
RU2732081C1 |
METHOD OF DISSOLVING MOX FUEL | 2010 |
|
RU2451639C1 |
DISSOLUTION METHOD OF OFF-GRADE AND/OR SPENT FUEL | 2009 |
|
RU2400846C1 |
METHOD OF PRODUCING SOLID PLUTONIUM DIOXIDE SOLUTION IN URANIUM DIOXIDE MATRIX | 2013 |
|
RU2554626C2 |
METHOD OF PRODUCING SOLID PLUTONIUM DIOXIDE SOLUTION IN URANIUM DIOXIDE MATRIX | 2015 |
|
RU2598943C1 |
METHOD FOR PRODUCING MIXED URANIUM AND PLUTONIUM OXIDES | 2015 |
|
RU2626854C2 |
WASTE NUCLEAR FUEL PROCESSING METHOD | 2014 |
|
RU2560119C1 |
METHOD OF PRODUCING MIXED URANIUM-PLUTONIUM OXIDE | 2017 |
|
RU2638543C1 |
Authors
Dates
2021-09-01—Published
2021-01-11—Filed