FIELD: metallurgy.
SUBSTANCE: invention relates to metallurgy, in particular to heat-resistant chromium-nickel alloys of the austenitic class with intermetallic hardening, and can be used in the production of reaction tubes for ammonia and methanol units with operating temperatures of 800-950°C and a pressure of 2.5-5 MPa and oil and gas processing plants with operating modes from 950 to 1160°С and pressure up to 0.7 MPa. The high-temperature alloy contains, wt.%: carbon 0.35÷0.45; silicon 1.0÷1.80; manganese 0.9÷1.60; chromium 28.0÷31.0; nickel 37.0÷40.0; niobium 0.9÷1.70; titanium 0.26÷0.50; cerium> 0÷010; lanthanum> 0÷0.10; zirconium> 0÷0.10; tungsten 0.05÷0.25; aluminum> 0÷0.12; vanadium> 0÷0.10; cobalt> 0÷0.10; molybdenum> 0÷0.10; sulfur ≤0.02; phosphorus 0.02; lead ≤0.007; tin ≤ 0.006; arsenic ≤ 0.006; zinc ≤ 0.006; antimony ≤0.007; nitrogen ≤ 0.01; copper ≤0.1; iron is the rest. The alloy has a structure consisting of an austenite matrix and intermetallic compounds Cr(24÷58)Fe(3÷6)Ni and Nb(26÷34)Cr(2,6÷3,4)(FeNiTi)(0,9÷1,1), with the mass ratio of the austenite matrix and intermetallic compounds (89÷95):(4÷10):(1÷3).
EFFECT: structure of the alloy is improved and the homogeneity of secondary carbides increases, high values of strength, heat resistance are provided, as well as the absence of cracks during pipe welding and during long-term operation.
1 cl, 2 ex
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Authors
Dates
2022-02-03—Published
2021-07-26—Filed