FIELD: organic chemistry.
SUBSTANCE: invention relates to the field of organic chemistry of heterocyclic compounds, in particular to synthon for the production of medicinal substances, corrosion inhibitors, dyes, insecticides. Disclosed is a method for producing 1,9-3',4'-dihydro-2H-benzo[b][1',4']oxazino-1,9-dihydro-(C60-Ih)[5,6]fullerene of formula (1 ), characterized in that C60 fullerene interacts with 2-aminophenol in air in the presence of solid LiOH and Pb(CH3COO)4 at a molar ratio of C60:2-aminophenol:LiOH:Pb(CH3COO)4=1:10:10:2.4, at a temperature of 40°C in toluene:Et2O=5:1 medium (volume ratio) for 1 hour and further stirring at room temperature on a magnetic stirrer for 23 hours. In addition, the use of 1,9-3',4'-dihydro-2H-benzo[b][1',4']oxazino-1,9-dihydro-( C60-Ih)[5,6]fullerene of the formula (1) as an agent with antioxidant (antiradical) activity.
EFFECT: invention provides effective antioxidant (antiradical) activity.
2 cl, 2 tbl, 1 ex
Title |
Year |
Author |
Number |
1,9-[3',3'-BIS(HYDROXYMETHYL)MORPHOLINO]-1,9-DIHYDRO-(C-I)[5,6]FULLERENE AS A COMPLEXING AGENT AND METHOD FOR ITS PREPARATION |
2022 |
- Kinziabaeva Zemfira Sabitovna
- Fazletdinova Zinfira Nasimovna
|
RU2807926C1 |
1,9-(2'-HYDROXYMETHYL-1',4'-DIOXANO)-1,9-DIHYDRO-(C-I)[5,6]FULLERENE AND ITS PRODUCTION METHOD |
2021 |
- Kinzyabaeva Zemfira Sabitovna
|
RU2785546C2 |
METHOD FOR OBTAINING 1,9-(1',4'-OXATHIANO-4'-OXIDE)-1,9-DIHYDRO-(C-I)[5,6]FULLERENE |
2022 |
- Kinziabaeva Zemfira Sabitovna
|
RU2785692C1 |
METHOD OF PRODUCING 1,9-(1',4'-OXATHIANO)-1,9-DIHYDRO-(C-I][5,6]FULLERENE |
2019 |
- Kinzyabaeva Zemfira Sabitovna
- Sharipov Glyus Lyabibovich
|
RU2730478C1 |
1,9-MORPHOLINO-1,9-DIHYDRO-(C -I)[5,6]FULLERENE AND METHOD FOR PRODUCTION THEREOF |
2020 |
- Kinzyabaeva Zemfira Sabitovna
- Sharipov Glyus Lyabibovich
|
RU2772722C2 |
METHOD FOR PRODUCING 1,9-N,N'-DIETHYL-ETHYLENEDIAMINO-1,9-DIHYDRO-(C-I)[5,6]FULLERENE |
2021 |
- Kinzyabaeva Zemfira Sabitovna
- Sharipov Glyus Lyabibovich
|
RU2767540C1 |
METHOD OF PRODUCING S-PENTYLCARBOTHIOL-1aH,2'H-[1,2]PYRAZOLINO[3',4':1,9](C-I)-[5,6]FULLERENE |
2012 |
- Dzhemilev Usein Memetovich
- Tuktarov Ajrat Ramilevich
- Khuzin Artur Al'Bertovich
|
RU2517169C2 |
METHOD OF PRODUCING N-ALKYL AND N-ARYLCARBOXAMIDYL-1aH,2'H-[1,2]PYRAZOLINO[3',4':1,9](C-I)-[5,6]FULLERENES |
2012 |
- Dzhemilev Usein Memetovich
- Tuktarov Ajrat Ramilevich
- Khuzina Lilija Linatovna
|
RU2517170C2 |
METHOD OF PRODUCING FULLERENE OXIMES: BIS-ADDUCTS OF 1-[HYDROXO]-9-[1'-HYDROXYIMINO-2'-OXO-2'-ALKYL-ETHYL]-1,9-DIHYDRO-[C-I][5,6]FULLERENES |
2015 |
- Bulgakov Ramil Garifovich
- Kinzjabaeva Zemfira Sabitovna
|
RU2605453C2 |
METHOD FOR SELECTIVE PRODUCTION OF 2',5'-UNSUBSTITUTED 1'-BENZYLPYRROLIDINO[3',4':1,9](C60-IH)[5,6]FULLERENES |
2017 |
- Dzhemilev Usein Memetovich
- Tuktarov Ajrat Ramilevich
- Khuzin Artur Albertovich
- Shakirova Zulfiya Rasimovna
|
RU2666726C1 |