FIELD: raw materials processing.
SUBSTANCE: invention relates to the processing of alumina-containing raw materials - bauxite and red mud, alumina production waste. Complex processing of alumina-containing raw materials includes preparation of a charge containing alumina-containing raw materials and soda in an amount of not more than 5% by weight of the charge, while limestone is contained while maintaining the CaO/SiO2 molar ratio (1.9-2.1):1. The mixture obtained is heated to a temperature of at least 350°C. Then heat treatment is carried out in a fluidized bed at 750-900°C in the presence of a reducing agent, which is carbon monoxide or a mixture of carbon monoxide and hydrogen. The mixture is cooled in an inert gas atmosphere, magnetic separation is carried out in a separator with a magnetic field induction of 300-900 mT on the working surface to obtain a magnetic fraction, which is an iron-containing product, and a non-magnetic fraction, including oxides of aluminum, calcium, silicon and dicalcium silicate. The non-magnetic fraction is subjected to mechanical activation in a vortex mill to a particle size of 7-10 mcm and sent for leaching with a sodium hydroxide solution with a concentration of 110-140 g/dm3 at a temperature of 65-90°C. The aluminate solution is separated from the white mud and sent to obtain alumina. The separated white sludge is washed from alkali and used to obtain foam silicates.
EFFECT: method provides for the complex processing of alumina-containing raw materials while reducing the energy intensity of the process with the production of high-quality iron-containing, aluminum-containing and calcium-silicate products suitable for further use.
4 cl, 5 tbl
Title | Year | Author | Number |
---|---|---|---|
BAUXITE CONCENTRATION PROCESS | 1997 |
|
RU2136378C1 |
METHOD OF ALUMINA CONTAINING RAW MATERIAL PROCESSING INTO ALUMINA | 2004 |
|
RU2326817C2 |
METHOD OF PRODUCING ALUMINA FROM CHROMIFEROUS BAUXITES | 2016 |
|
RU2613983C1 |
METHOD OF PROCESSING ALUMINUM-CONTAINING RAW MATERIAL | 2006 |
|
RU2313491C1 |
METHOD OF CONVERSION OF BAUXITES INTO ALUMINA | 2003 |
|
RU2232716C1 |
ALUMINA PRODUCTION PROCESS | 2000 |
|
RU2200708C2 |
METHOD OF ALUMINO-CALCAREOUS SLAGS RECEIVING | 2007 |
|
RU2356955C2 |
PROCEDURE FOR RED MUD PROCESSING | 2009 |
|
RU2428490C2 |
METHOD OF PROCESSING BAUXITES INTO ALUMINA | 2012 |
|
RU2494965C1 |
METHOD OF PROCESSING OF BAUXITES INTO ALUMINA | 1999 |
|
RU2181695C2 |
Authors
Dates
2023-01-10—Published
2022-05-20—Filed