FIELD: organic chemistry. SUBSTANCE: product - 2-substituted 6-methoxy-1,3-oxazine-4-ones of the general formula where R - 2-furyl (1), p-tolyl (2), p-methoxyphenyl (3), and p-chlorophenyl (4). Empirical formula, yield (%), and m. p. (C) for compound (1) are: C4H7NO4,, 82, 148-150; for compound (2): C12H11NO4,, 51, 133-134; for compound (3): C12H11NO4,, 52, 120-123; for compound (4): C11H8ClNO3,, 85.5, 140-142. Reagent 1: R - CONCO. Reagent 2: methoxyacetylene. Reaction conditions: in the medium of dichloroethane or benzene at 5-10 C. EFFECT: improved method of synthesis. 2 tbl
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Authors
Dates
1995-01-20—Published
1990-07-20—Filed