FIELD: organic chemistry. SUBSTANCE: product - mixture of polyphenylene-polymethylene-polyisocyanates. Reagent 1: isocyanatocarbamoyl chloride obtained by condensation of aniline with formalin following by phosgenation. Reagent 2: phenylisocyanate (1-3 mole per 1 mole formalin). Reaction conditions: heating at 150-170 C in the presence of catalyst - ammonium, zinc, iron, tin chlorides taken at concentration 1-3 % by weight of reaction mass mixture. EFFECT: improved method of synthesis. 2 tbl
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Authors
Dates
1994-02-15—Published
1991-06-10—Filed