FIELD: organic chemistry. SUBSTANCE: product: derivatives of pyrimidine of the general formula (I) where R lower imidazole or alkylthio-group, or group of the formula OR3 where R3 hydrogen, alkyl possibly substituted with cyano-, alkoxy-, alkylthio-, phenyl, phenylthio-, phenylsulfinyl, phenylsulfonyl, benzylhydroxy-, alkylcarbonyloxy-, alkoxycarbonyloxy- or phthalimidoyl-group; or R3 alkenyl, alkynyl, alkylydeneamino-group, alkaline metal or group -CH2-C(O)-R4 where R4 phenyl or alkyl; R1 hydrogen or alkyl; R2 hydroxy, alkoxy-group possibly substituted with halogen, phenoxy-, benzyloxy-, alkylhydroxycarbonyl, cycloalkyl-C3-C6 or alkoxy-group, or R2 alkenyl possibly mono- or disubstituted with halogen or phenyl, alkynylhydroxy-group, phenyl possibly substituted with halogen, alkyl or alkoxy-group, phenoxy-group, benzylhydroxy-group possibly substituted with halogen, alkoxy-group, phenylamino-group or group -OC(O)R5 where R
where R hydroxy-, alkoxy or benzylhydroxy-group; R1 hydrogen, lower alkyl; A and B alkoxy-group; Y oxygen or sulfur and also phenyl-derivatives of the formula (III)
where Y oxygen; R - hydroxy- or alkoxy-group; R1 alkyl. Alkyl in indicated substituents is lower one; R2 phenyloxy- or benzyloxy-group, and these compounds are intermediate products for synthesis of compounds of the formula (I). Method of struggle against weed is carried out by treatment of plants or areas where plants were grown with compound of the formula (I) taken at concentration 0.016-1 kg/ha. Herbicide composition has active components compounds of the formula (I) at concentration 2-30 wt. -% and the special additions the rest. Synthesized compounds were used in agriculture. EFFECT: improved method of synthesis. 6 cl, 14 tbl
Title | Year | Author | Number |
---|---|---|---|
PYRIMIDINE DERIVATIVES | 1992 |
|
RU2028294C1 |
PYCOLINIC ACID DERIVATIVES OR ACID ADDITION SALTS, METHOD OF PREPARATION THEREOF, HERBICIDAL COMPOSITION AND METHOD OF CONTROLLING WEEDS | 1991 |
|
RU2091380C1 |
NICOTINIC ACID DERIVATIVES, METHOD OF PREPARATION THEREOF, AND HERBICIDAL COMPOSITION | 1994 |
|
RU2133746C1 |
CONDENSED HETEROCYCLIC DERIVATIVE, METHOD OF ITS SYNTHESIS AND HERBICIDE AGENT | 1993 |
|
RU2105005C1 |
PYRIMIDINE DERIVATIVES | 1992 |
|
RU2049781C1 |
ALKANIC ACID AMIDE DERIVATIVES, PROCESSES FOR PREPARATION THEREOF, HERBICIDAL COMPOSITION, AND METHOD OF CONTROLLING WEEDS | 1991 |
|
RU2061687C1 |
DERIVATIVES OF N-SULFONYLCARBOXYLIC ACID AMIDE INCLUDING N-CONTAINING 6-MEMBERED AROMATIC RING, FUNGICIDE AND HERBICIDE COMPOSITION AND METHODS OF STRUGGLE AGAINST WEEDS AND PATHOGENIC FUNGI | 1993 |
|
RU2117662C1 |
WEED CONTROL METHOD | 0 |
|
SU1807848A3 |
WEED CONTROL METHOD | 1988 |
|
RU2024227C1 |
CONDENSED HETEROCYCLIC DERIVATIVES, METHODS OF THEIR SYNTHESIS, COMPOSITION BASED ON THEREOF, A METHOD OF CONTROL OVER FUNGI | 1993 |
|
RU2098408C1 |
Authors
Dates
1995-08-09—Published
1990-12-27—Filed