FIELD: organoaluminium compounds. SUBSTANCE: synthesis is carried out by reaction of dicyclopentadiene with diethylaluminium chloride at their molar ratio 10:(10-12), mainly at 10:11, at the room temperature (23-25 C) and under normal pressure, in the presence of bimetallic catalyst titanium tetrachloride with iso-dibutylaluminium chloride (1:1) taken at concentration 2-5 (preferably 3) mole with relation to dicyclopentadiene, in argon atmosphere, in the medium of aliphatic solvent (hexane, heptane or cyclohexane). Reaction time is 8-12 h, yield of the end products is 70-82% EFFECT: improved method of synthesis. 1 tbl
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| METHOD OF COMBINED SYNTHESIS OF 1-(ENDO- TRICYCLO-[5.2.1.0] -DEC-7-ENE -2-YL)-1- (ISOBUTYL)-1-CHLORALANE AND 1-(ENDO- TRICYCLO- [5.2.1.0]-DEC -6-ENE- 2-YL) -1- (ISOBUTYL) -1-CHLORALAN- E |
1992 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Minsker D.L.
- Shitikova O.V.
|
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1992 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Minsker D.L.
- Shitikova O.V.
|
RU2030417C1 |
| METHOD FOR PRODUCTION OF TRANS-5,6-DI(SUBSTITUTED)-HEPT-1-ENES |
1993 |
- Ibragimov A.G.
- Azhgaliev M.N.
- Muslukhov R.R.
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2002 |
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- Khafizova L.O.
- Jakupova L.R.
- Prokhorova N.A.
- Islamgulova A.Z.
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RU2231528C2 |
| METHOD OF SYNTHESIS OF 1-ETHYL-2-(2'-PHENYLETHYLENE)-3-PHENYL- -ALUMOCYCLOPROPANE |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
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RU2146679C1 |
| METHOD OF SYNTHESIS OF 1,4-BIS-(DIALKYLALUMINO)-TRANS-2,3-DIALKYLBUTANES |
1992 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Azhgaliev M.N.
- Muslukhov R.R.
|
RU2043356C1 |
| METHOD OF SYNTHESIS OF 1-ETHYL-2-PHENYLALUMACYCLOPROPANE |
1996 |
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- Sultanov R.M.
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RU2152395C1 |
| METHOD OF PREPARING 2-CHLORO-2-ALUMABICYCLO [3,2,2,] NONANE |
1998 |
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- Sharifullina F.M.
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RU2139880C1 |
| METHOD OF COMBINED PREPARATION OF 1-ETHYL-2- PHENYLALUMACYCLOPROPANE AND 1-ETHYL-2,4- DIPHENYLALUMACYCLOPENTANE |
1996 |
- Dzhemilev U.M.
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RU2153499C2 |
| METHOD OF PREPARING 1-ETHYL-3-ALKYLBOROCYCLOPENTANES |
1997 |
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- Kunakova R.V.
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RU2129558C1 |
