FIELD: organic synthesis. SUBSTANCE: at the first stage addition product of 1,2-dichloro-1,2,2-trifluoroiodoethane and vinyl acetate is prepared. The process is carried out in aqueous-acetonitrile solution in the presence of mixture of sodium dithionite and sodium bicarbonate. Then thus obtained product is treated by suspension of zinc in ethanol and by hydrochloric acid. The process is followed by extraction thus prepared product with chloroform or with methylene chloride or carbon tetrachloride and by distillation of solvent. At the third stage product being prepared at the second stage is treated by mixture of zinc dust in glycol, the process takes place at 130-150 C. EFFECT: simplified process, decreased energy expense.
| Title |
Year |
Author |
Number |
| 1-IODO-3,4-DICHLORO-3,4,4-TRIFLUOROBUTYL ACETATE AS INTERMEDIATE PRODUCT FOR PRODUCTION OF 1,1,2-TRIFLUORO-1-BUTENE-4-OL BEING USED IN SYNTHESIS OF POLYFLUORINATED SURFACTANTS FOR COPOLYMERIZATION AND PRODUCTION OF ELECTROLYTES |
1995 |
- Gorbunova T.I.
- Zapevalov A.Ja.
- Saloutin V.I.
|
RU2074168C1 |
| METHOD OF SYNTHESIS OF 1,1,2,3,3-PENTAFLUORO-1,5-HEXADIENE |
1991 |
- Gorbunova T.I.
- Podol'Skij A.V.
- Saloutin V.I.
|
RU2022955C1 |
| 2-IODO - 4,5 - DICHLORO - 4,5,5 - TRIFLUOROPENTYLACETATE AS AN INTERMEDIATE COMPOUND FOR SYNTHESIS OF 1,1,2 - TRIFLUORO - 1,4 - PENTADIENE USED FOR POLYFLUORINATED SURFACE-ACTIVE SUBSTANCES SYNTHESIS |
0 |
- Gorbunova Tatyana Ivanovna
- Podolskij Arnold Veniaminovich
- Saloutin Viktor Ivanovich
|
SU1810329A1 |
| DIMETHYL ETHER (2S,4RS)-N-PHTHALOYL-4-IODOGLUTAMIC ACID AS SYNTON FOR PRODUCTION OF -DERIVATIVES OF GLUTAMIC ACID AND METHOD FOR THEIR PRODUCTION |
1994 |
- Koroleva M.A.
- Evstigneeva N.G.
- Krasnov V.P.
|
RU2078763C1 |
| PROCESS FOR PREPARING INDIVIDUAL STEREOISOMERS OF 4- SUBSTITUTED GLUTAMIC ACID THIODERIVATIVES |
1994 |
- Krasnov V.P.
- Bukrina I.M.
- Koroleva M.A.
- Kodess M.I.
|
RU2083560C1 |
| METHOD OF POLYCHLORINATED DIPHENYL CHEMICAL PROCESSING |
1995 |
- Chupakhin O.N.
- Zapevalov A.Ja.
- Gorbunova T.I.
- Saloutin V.I.
|
RU2087458C1 |
| METHOD OF SYNTHESIS OF TRIFLUOROACRYLIC ACID FLUOROANHYDRIDE |
1992 |
- Zapevalov A.Ja.
- Gorbunova T.I.
- Saloutin V.I.
|
RU2035449C1 |
| SUBSTITUTED DI-(FORMYLARYL)-POLYESTERS OR THEIR COORDINATION COMPOUNDS OR THEIR PHARMACEUTICALLY ACCEPTABLE ADDITIVE SALTS, METHOD OF THEIR SYNTHESIS AND PHARMACEUTICAL COMPOSITION ON SAID |
1998 |
- Chupakhin O.N.
- Fedorova O.V.
- Rusinov G.L.
- Mordovskoj G.G.
- Khomenko A.G.
- Golyshevskaja V.I.
- Zueva M.N.
- Ovchinnikova I.G.
|
RU2137750C1 |
| METHOD OF SYNTHESIS OF FLUORINE-CONTAINING $$$-DIKETONES |
1995 |
- Ratner V.G.
- Khomutov O.G.
- Karpenko N.S.
- Filjakova V.I.
- Pashkevich K.I.
|
RU2100345C1 |
| METHOD OF DETERMINING LOWER ALKYLMERCAPTANS |
1993 |
- Osipova O.A.
- Kirichenko V.E.
- Pashkevich K.I.
|
RU2117942C1 |
