FIELD: agriculture. SUBSTANCE: present invention describes optically active 2-imidazolin-5-one derivatives of general formula 1: wherein W is oxygen atom, M is oxygen or sulfur atom; R1 and R2 are different and are alkyl or phenyl substituted by 1-3 groups selected from R6;; R3 is C1-2алкил alkyl; R4 is H or phenyl optionally substituted by 1-3 groups selected from R6; R5 is H except that when R4 is H or phenyl optionally substituted from R6; R6 is halogen or phenoxy optionally substituted by halogen atom. Said compounds are prepared by reacting compound of formula II: , wherein W is oxygen atom, with compound of formula R3X wherein X is chlorine, bromine or iodine atom or sulfate group or alkylsulphonyloxy- or arylsulfonyloxy group. Compositions based on compounds of formula I are useful as fungicidal agents. EFFECT: improved properties of the fungicidal composition. 11 cl, 10 ex, 11 tbl
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