METHOD OF SYNTHESIS OF (1 + 1)-ADDUCTS OF C-FULLERENE WITH NORBORNADIENE AND ITS 7-SPIROCYCLOPROPANE-SUBSTITUTED DERIVATIVE Russian patent published in 1999 - IPC

Abstract RU 2137743 C1

FIELD: organic chemistry. SUBSTANCE: method involves reaction of cyclo-addition of norbornadiene or 7-spirocyclopropane bornadiene to C60-fullerene in chlorobenzene or 2-methylthiophene medium at 160-180 C for 5 h in excess of norbornadiene and 7-spirocyclopropane norbornadiene up to 50-200 times. Under these conditions the yield of end substances is 80%. EFFECT: high selectivity of process, simplified procedure. 1 tbl, 16 ex

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RU 2 137 743 C1

Authors

Khusnutdinov R.I.

Gajnullin Kh.Kh.

Muslimov Z.S.

Dzhemilev U.M.

Nefedov O.M.

Tomilov Ju.V.

Dates

1999-09-20Published

1998-04-29Filed